Ebook Modern Physical Organic Chemistry, by Eric V. Anslyn, Dennis A. Dougherty
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Modern Physical Organic Chemistry, by Eric V. Anslyn, Dennis A. Dougherty
Ebook Modern Physical Organic Chemistry, by Eric V. Anslyn, Dennis A. Dougherty
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This is the first modern textbook, written in the 21st century, to make explicit the many connections between physical organic chemistry and critical fields such as organometallic chemistry, materials chemistry, bioorganic chemistry, and biochemistry. In the latter part of the 20th century, the field of physical organic chemistry went through dramatic changes, with an increased emphasis on noncovalent interactions and their roles in molecular recognition, supramolecular chemistry, and biology; the development of new materials with novel structural features; and the use of computational methods. Contemporary chemists must be just as familiar with these newer fields as with the more established classical topics. This completely new landmark text is intended to bridge that gap. In addition to covering thoroughly the core areas of physical organic chemistry – structure and mechanism – the book will escort the practitioner of organic chemistry into a field that has been thoroughly updated . The foundations and applicabilities of modern computational methods are also developed. Written by two distinguished researchers in this field, Modern Physical Organic Chemistry can serve as a text for a year-long course targeted to advanced undergraduates or first-year graduate students, as well as for a variety of shorter courses on selected aspects of the field. It will also serve as a landmark new reference text, and as an introduction to many of the more advanced topics of interest to modern researchers. An accompanying Student Solutions Manual will become available.
- Sales Rank: #52502 in Books
- Brand: Brand:
- Published on: 2005-07-15
- Released on: 2005-07-15
- Original language: English
- Number of items: 1
- Dimensions: 11.12" h x 2.17" w x 8.88" l, 6.16 pounds
- Binding: Hardcover
- 1104 pages
Features
- Used Book in Good Condition
Review
"It will certainly inspire." -- Barry Carpenter, Cornell University
"This book is the new authoritative physical organic resource that will benefit researchers, students, and teachers alike." -- Timothy Swager, Massachusetts Institute of Technology
"This book is the new authoritative physical organic resource that will benefit researchers, students, and teachers alike.” --Timothy Swager, Massachusetts Institute of Technology
"This much needed text places physical organic chemistry in its most modern context." -- Timothy M. Swager, MIT
I can enthusiastically recommend the text." --Nicholas J. Turro, Columbia University
About the Author
Eric V. Anslyn received his PhD in Chemistry from the California Institute of Technology under the direction of Robert Grubbs. After completing post-doctoral work with Ronald Breslow at Columbia University, he joined the faculty at the University of Texas at Austin, where he became a Full Professor in 1999. He currently holds four patents and is the recipient of numerous awards and honors, including the Presidential Young Investigator, the Alfred P. Sloan Research Fellow, the Searle Scholar, the Dreyfus Teacher-Scholar Award, and the Jean Holloway Award for Excellence in Teaching. He is also the Associate Editor for the Journal of the American Chemical Society and serves on the editorial boards of Supramolecular Chemistry and the Journal of Supramolecular Chemistry. His primary research is in physical organic chemistry and bioorganic chemistry, with specific interests in catalysts for phosphoryl and glycosyl transfers, receptors for carbohydrates and enolates, single and multi-analyte sensors – the development of an electronic tongue, and synthesis of polymeric molecules that exhibit unique abiotic secondary structure. Dennis A. Dougherty received a PhD from Princeton with Kurt Mislow, followed by a year of postdoctoral study with Jerome Berson at Yale. In 1979 he joined the faculty at the California Institute of Technology, where he is now George Grant Hoag Professor of Chemistry. Dougherty's extensive research interests have taken him to many fronts, but he is perhaps best known for development of the cation- interaction, a novel but potent noncovalent binding interaction. More recently, he has addressed molecular neurobiology, developing the in vivo nonsense suppression method for unnatural amino acid incorporation into proteins expressed in living cells. This powerful new tool enables “physical organic chemistry on the brain” - chemical-scale studies of the molecules of memory, thought, and sensory perception and the targets of treatments for Alzheimer's disease, Parkinson's disease, schizophrenia, learning and attention deficits, and drug addiction. His group is now working on extensive experimental and computational studies of the bacterial mechanosensitive channels MscL and MscS, building off the crystal structures of these channels recently reported by the Rees group at Caltech.
Most helpful customer reviews
14 of 14 people found the following review helpful.
A fantastic text for reading or for reference
By copper
Anslyn and Dougherty's is arguably the single most useful text, on any subject, available to chemists today. Although physical organic chemistry could easily be viewed as a narrow, arcane subject, these authors demonstrate that this is far from the truth. Anslyn and Dougherty have done a marvelous job of presenting a truly unbelievable amount of material in a way that is not only approachable, but also quite detailed and comprehensive. It is often said that the more accessible texts are a mile wide and an inch deep. This text is a mile wide and a mile deep (not entirely surprising, considering it is also arguably the bulkiest text available to chemists today!). If you can think of it, you can probably find it in the index. I would add that this text has a fantastic, 20-page (!) index, something many of the older texts ought to take a lesson from.
The best texts, in any discipline, do not teach anything outside of a practical context. Anslyn and Dougherty present a truly astonishing array of "Connections" boxes, one on almost every page, which explicate real examples from the literature of the section's principles being applied. The reader whose interest is piqued by a particular section will thus find several excellent starting places in the primary literature for further study. As many other reviewers have noted, this is a modern text that stresses interdisciplinary connections. As an example, the Felkin-Anh model of nucleophilic addition to carbonyls is presented as a practical example of the Curtin-Hammett principle. Although this connection may seem obvious to the initiated, it is not the kind of thing that the majority of texts (let alone professors!) emphasize. Nevertheless, discovering these connections is the only way a student will ever begin to think critically about a subject. Anslyn and Dougherty put students on the right track.
What is most remarkable, however, is that this text could easily (and willingly!) be read by motivated undergraduates. The first chapter is an outstanding summary of the theory of chemical bonding, a subject whose fundamental importance cannot be overstressed. This chapter, the third chapter on solutions and non-covalent binding forces, the fifth on acids and bases, and several others, would each be worth the price of the book alone. I would seriously recommend that motivated undergraduates attempt to read through as much as possible of this text. It's lucid, concise, and genuinely a joy to read. If you only read one textbook all the way through in your young career, make this one it.
I should mention that the negative reviewer speaks the truth about this book's binding. I don't think I have ever seen such a flimsy binding on such a large textbook, but I suppose it keeps the cost under control. With new copies floating around for $100, this book really is a steal. Mine is still holding up just fine, but I am also very kind to my books. The way some people treat theirs, I would be very concerned about it falling apart.
10 of 27 people found the following review helpful.
Poor quality printing brings down the quality of the text
By JL
The textbook is of very poor physical quality. I have never had a textbook with binding as cheap as this one. The binding started peeling apart the day after I got it and it is nearly totally ripped out in less than a month. Other textbooks I have used have stood up to months or years of frequent use without this problem.
The book has a lot of detail, but this can be overwhelming. It isn't a terribly exciting read even considering it is a textbook. The number of sidebars in the book is distracting at times, as there is nearly one per page in many sections. I have found a small smattering of typographical errors, but no more than is expected in a first edition. The good news is that the printing is in 2 colors only and has minimal pictures which probably helped to keep the cost of printing lower. For serious study, the text is good even if the book quality itself is poor.
7 of 7 people found the following review helpful.
The Best Book on Physical Organic Chemistry
By Ken from Doylestown
I have been a professional chemist for more than 30 years. This book is probably the best on physical organic chemistry that I have ever come across. The book is over 1000 pages in length. I read the book from cover to cover. There is not a single chapter that is boring. The book covers a wide range of topics in physical organic chemistry. These topics include molecular structures, stereochemistry, conformational analysis, molecular recognition and supramolecular chemistry, acid and base chemistry, thermodynamics, kinetics and mechanism, organometallic chemistry, polymers, organic electronic theory, pericyclic reactions, photochemistry and organic materials. The treatment of each topics is well beyond elementary level. It is the intent of the authors that the book will be able to provide the necessary background for reading current research literature. Excercises are provided at the end of each chapter. The problems in the Excercises Section are interesting and challenging. I strongly encourage any graduate student to attempt these problems. Many interesting examples are given throughout each chapter. To illustrate, here is an interesting example given in the chapter of "Advanced Concepts in Electronic Structural Theory". Using the simple Huckel molecular orbital analysis, the two molecules cyclobutadiene (CBD) and trimethylenemethane (TMM) are known to have the same molecular orbital pattern for their pi electrons. In other words, these two molecules have one bonding orbital, two degenerate non-bonding orbitals and one anti-bonding orbital. Both are 4-electron systems. We therefore expect that there will be two unpaired parallel spin electrons in the degenerate non-bonding orbitals. Both molecules would have a triplet ground state. However, more advanced analysis shows that the spin preferences of the two systems are different. CBD is expected to exist as a singlet ground state while TMM is expected to exist as a triplet state. The authors provide an extremely clear explanation for such an analysis. In the case of CBD, the two non-bonding orbitals are disjoint. Two molecular orbitals are said to be disjoint when there are no atoms in common in their LCAO's. Consequently, the exchange integral of the two electrons in the two non-bonding orbitals are zero. When electron correlation is incorporated into the analysis, CBD is found have a singlet ground state with a rectangular structure, instead of a perfect square, of alternate double and single bond. This is sometimes known as pseudo Jahn-Teller distortion. In the case of TMM, the non-bonding orbitals are non-disjoint. The exchange integral consequently is non-zero and a triplet ground state is preferred. This concept of spin preference is used to explain one of the strategies used in the synthesis of magnetic organic material. Examples of applications of physical organic chemistry principles to biological systems and technologies (such as liquid crystal) are also found throughout the book.
Beyond any doubts, this book is going to be the standard text for graduate students in organic chemistry for many years to come. If after reading this book and your interest in physical organic chemistry is not aroused, I do not believe that I will be able to find you a more interesting book on physical organic chemistry. The only criticism that I want to make is that I wish the authors would cover more on density functional theory. This part of theoretical chemistry is fast becoming more and more popular in current research. I also hope that the authors will update the book frequently.
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